Answers?
Stephen Shepherd in the State of Deseret
>Bill,
First of all, I don't know why glue works! But then again neither does anyone else, still a mystery as to exactly why any glue works. Given that there is still a lot of information about how glue behaves.
You wrote: 'To glue two pieces of metal together (or glass) a perfect smooth surface and an adhesive that will wet this surface is best. Is there something about wood or wood adhesives that require the adhesive to penetrate the wood structure to get a good bond? And if penetration is required, why is the porous structure of wood not sufficient to provide for penetration such that roughening would be beneficial?'
When you are gluing two non porous materials together you get a hydrogen and chemical bond and somewhat of a mechanical bond, which can hold very well depending upon surface preparation, cleaning and etching. (The garlic trick works great-an aside during my research I now know the intimate details of the chemistry of the garlic).
With porous materials such as wood you get a mechanical bond that physically holds the materials together, together with the other types of adhesive bonding that takes place, chemical, covalent, hydrogen, etc. The pores do help somewhat but the glue may not penetrate the holes because of trapped air within the pores. Sizing the boards prior to gluing will help.
Toothing or keying the surface increases the surface area of the glue joint and provides a mechanical device for the glue to bond to. An added benefit is that it is more difficult to starve the joint by excessive clamp pressure.
Application of glue to both surfaces is required for hide glue and this insures that both surfaces are 'wet' (surface tension wet). Putting the pieces together then pulling them apart to check for coverage actually sets up a bit of a capacitance discharge and can attract dust to the joint, Loudon levels and such.
I hope that answers your questions.
Stephen