Maybe.....
David Miller from Iowa
>Used to do some professional glazing back in the day. A local church had some stained/leaded glass windows - single pane and not very energy efficient. During the 70s energy crisis, they decided to put plexiglass over the outside to make another pane. Worked good until a summer heatwave and direct sunlight baked the windows until the lead got soft and the windows sagged like you wouldn't believe. We took them out, laid them on the blacktop parking lot in the sun and built a frame and put plastic sheet over it - sort of a solar oven. It straightened them out quite a bit but they never were really the same.
Possible your window was stored horizontally in a hot location and that caused the sag.
Maybe it will fit in your oven. 450 degrees might do it although I would modulate the temperature change very slowly (disclaimer - do at your own risk, I'm not sure this will work, you would be crazy to listen to me, etc.) It would be great if you had another sacrifical piece to test this on.