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Will varnishing indoors present explosion hazard

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Will varnishing indoors present explosion hazard

#1

Will varnishing indoors present  explosion hazard

Bill Tindall, E.Tn.

I was asked this question in an email. The answer:

There are two flammability issues. Will varnish burn? Yes, and a burning can of varnish in the shop will be a problem a small fire extinguisher can't fix. Can one generate enough combustible stuff in the shop air to explode? see below

One starts with data easily found on the Internet, the lower explosive limit, LEL, for mineral spirits. Below this concentration the flame from an ignition source will not propagate and the fuel air mix will not explode. LEL for mineral spirits is 0.7 volume percent. Translated, it means that 0.7% of the air needs to be mineral spirits before the air/mineral spirits mix will explode. What one wants to know is how much mineral spirits do I need to evaporate in a room of so many cubic feet to reach the LEL. To get to this value requires some recollection of chemistry gas laws to get a good approximation.

A mole of a volatile substance occupies 22.4 liters. 0.7% or 22.4 L is 0.16L. So 0.16L of mineral spirits vapor in 22.4 L of air will reach the LEL. 0.16L of mineral spirits vapor is 0.16/22.4 moles of mineral spirits. If we estimate the molecular weight of mineral spirits as about 200 we get 1.4 grams of mineral spirits vapor in 22.4 liters of room air will reach the LEL. A cubic meter is 1000 liters. 1000/22.4 X 1.4 g = 63 grams. It takes 63 grams of mineral spirits per cubic meter of air to reach LEL. A quart of varnish, at 30% solids would contain about 630 grams of mineral spirits, or enough to take 10 cubic meters of air to the LEL. A cubic meter is 35 cubic feet. That would equal a shop 2' x2' x 8' tall.

From here out you are on your own to make assumptions. What safety factor to build in, probably about 1/10 LEL. How far away is ignition source from mineral spirits evaporation? What is evaporation rate? What is rate of turnover of air in the room? Making reasonable assumptions yields t " use mineral spirits in a well ventilated space". Now where have you seen that warning before? Doing so will present no explosion hazard in the room." However, spilling the can of varnish on an ignition source will in itself present problems. I have no doubt that painters in 1950 smoked while painting rooms with mineral spirits formulated paint and varnish.

Re: Will varnishing indoors present explosion hazard

#2

lacquer

Bill Tindall, E.Tn.

Lacquer solvent has a lower molecular weight so it takes significantly less grams per air volume to reach its LEL. And it volatilizes much faster to challenge room air turnover. I have no doubt that painters who smoked while lacquering indoors didn't reach retirement age.

Re: Will varnishing indoors present explosion hazard

#3

Jesper, Denmark

Re: lacquer

Jesper, Denmark

Generally speaking, Bill, it is very unpleasant to be in a room with anywhere near the LEL af HC solvents. Hence, as a rule of thumb, if it just smells a bit, but is not eyewatering to be in the room, the chances of being anywhere near the LEL is very small.

A better experession is really LFL, Lower Flammable Limit, as the combustion is not with a flame front anywhere near an explotion.

So, ventilate till it is a comfortable atmosphere to work in, and the only place near the LFL is just over and in the open can.

Re: Will varnishing indoors present explosion hazard

#4

agree, correction, in addition- important folloup

Bill Tindall, E.Tn.

It is true that the LEL is greater than a concentration of vapor one would tolerate working in. But a LEL could exist where your nose isn't. That is the danger.

Lower flammability limit, LFL, and lower explosion limit, LEL, are equivalent.

"and the only place near the LFL is just over and in the open can."

While the container one is working from is a potential source of LEL that is not the area of greatest evaporation rate. The greatest rate of flammable vapor generation is at the application site. Not so much with a slow evaporating solvent like mineral spirits, which is why mineral spirits is used instead of naptha. But the application site is a significant risk with fast evaporating lacquer. Spraying generates a higher rate of vapor generation than brushing.

Another concern is the heavy flammable vapor sinking into a poorly ventilated area and concentrating.

Bottom line, the good ventilation needs to be where the application is occurring.

Re: Will varnishing indoors present explosion hazard

#5

Re: lacquer

Barry Irby

Several decades ago I was a builder. I pulled up at one of my houses only to see the floor finishers swirling around like angry bees. Turns out the house had about 300 sf of hardwood and they had applied a coat of lacquer. Padded on a liberal coat. The plan was to wait a while and put on a second coat. They liked lacquer because it dried quickly and they could do two coats in a morning. They had all the windows open. Somehow the fumes found an ignition source and it went BOOM. Boom maybe and over statement, more like foom. Kind of like when the cook flambes the cherries jubilee. It was over so fast they did not even have time to foul their pants. They buffed the floor and applied another coat and the floor served its purpose for about ten years. Then we moved some walls around and patched it and refinished it. Appeared to do no harm, other than to make believers out of the floor finishers.

When I apply finish in my shop I leave the DC hose nearby and run it to remove as much of the fumes as possible. The exhaust goes out side and the motor while not explosion proof is TEFC.

Re: Will varnishing indoors present explosion hazard

#6

Nothing like a good illustration


Re: Will varnishing indoors present explosion hazard

#7

Re: lacquer

Hank Knight

There was a young local man that had become a very good at reconditioning pianos. He had a small shop where he worked alone. About 20 years ago he was refinishing a piano and spraying lacquer in his shop. Something ignited the ambient lacquer solvent; the speculation was the pilot light in his water heater was the ignition source. There was a terrible explosion that wrecked his shop. He was severely burned and died from his injuries several weeks later.

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