Re: Water Resistance for Hot Hide Glue?
Rum
Near the bottom of this long lost (but thankfully saved) web page is an process that is purported to work with "alum" (aka aluminum sulfate or potassium - one may work better than the other - I don't know).
The naive adding of it to the glue pot reportedly renders the mix into a goober like substance that is at best difficult to clean out of the gluepot.
You might also look at casein glues although I'm currently unaware of any commercial ones (they may exist).
https://web.archive.org/web/20010609020446/http://www.dioptra.com/khill/articles/varnish.html
Re-quoted here for convenience and posterity.
"I found this method and adapted it from a book called Henley's Formulas. It can not be found in the section heading of glues or waterproof glues. Rather it is hidden somewhere in the book under another heading which I can't remember. In fact, the author describes the accident that caused the discovery but only as it related to something else.>
My method for making waterproof hide glue is as follows: make a super saturated solution of alum (aluminum sulfate). Next, take one teaspoon of this solution and add it to a quart of water. Then use this water to soften your glue granules. When the glue has absorbed what water it will, heat it and use it. You can not add more solution to the glue once it has been heated as it will cause the glue to coagulate into a single lump. But you can thin this "alumed" glue with tap water. I use a convex glass plate to cover my glue; it allows the condensate to drip back into the pot. Because of the presence of alum, this glue resists spoilage for some time. I find also that it can be allowed to cool, chilled and reheated several times before it begins to disintegrate."